姓名：郝二宏
性別：男
出生年月：
職稱：教授
學院：化學與材料科學學院
研究方向：

所受教育
1996．9-2000．8，山東大學化學系, 本科；
2000．9-2003．8，中國科學技術大學化學系，碩士，導師：王官武教授；
2003．8-2007．12，美國路易斯安娜州立大學化學系，博士，導師：Graca Vicente 教授。

職稱職位
2008 年 1 月 –現(xiàn)在: 安徽師范大學化學與材料科學院，安徽師范大學引進“雙十”人才

主持項目
“新型四氮配體金屬催化劑的設計合成及性能研究”（國家自然科學基金項目，2010-2012，主持)
“新型金屬corrole衍生物合成及催化性能研究”（教育部留學回國人員基金項目，2010-2012，主持）
“新型近紅外光敏劑的合成與性能研究”（教育部博士點新教師基金 2010-2012，主持）
“卟啉烯衍生物的全合成與性能研究”（安徽省教育廳重點項目，2009-2011，主持）
“金屬卟啉自組裝超分子體系的設計合成及其對三聚氰胺類分子的識別性能研究” (安徽自然科學基金，2009-2011，主持)
“新型4-氮配體的設計合成及催化性能研究”（安徽師范大學“雙十”人才啟動基金，2008-2011，主持）

研究領域
有機合成
有機功能材料設計
多氮配體催化劑分子設計

講授課程
有機化學
綜合化學實驗

獲獎情況
2002年 中國科學技術大學光華獎學金
2005年 Colgate-Palmolive and LSU Chemistry Department Award for Excellence in Research
2006-2008年 LSU Charles Coates Research Award
2006-2007年 LSU Graduate School Dissertation Fellowship
007-2008年 LSU Charles Coates Outstanding Dissertation Award

發(fā)表論文
Fabre, B.; Hao, E. H.; LeJeune, Z. M.; Amuhaya, E. K.; Barriere, F.; Garno, J. C.; Vicente, M. G. H. Polythiophenes Containing In-Chain Cobaltabisdicarbollide Centers. ACS Appl. Mater. Interfaces ASAP, DOI: 10.1021/am9007424.
Hao, E. H.; Wang, Z. Y.; Jiao, L. J.; Wang, S. W.; “Click” Tetradentate Ligands. Dalton Trans. 2010, 39, 2660-2666.
Hao, E. H.; Jensen, T. J.; Vicente, M. G. H. Synthesis of porphyrin-carbohydrate conjugates using “click” chemistry and their preliminary evaluation in human HEp2 cells. J. Porphyrins Phthalocyanines 2009, 13, 51-55.
Jiao, L. J.; Yu, C. J.; Li, J. L.; Wang, Z. Y.; Wu, M.; Hao, E. H. β-FormylBODIPYs from Vilsmeyer-Haack Reaction. J. Org. Chem.2009, 74, 7525-7528.
Barriere, F.; Fabre, B.; Hao, E. H; LeJeune, Z. M.; Hwang, E.; Garno, G. C.; Nesterov, E. E.; Vicente, M. G. H. Electropolymerizable 2,2′-Carboranyldithiophenes. StructureProperty Investigations of the Corresponding Conducting Polymer Films by Electrochemistry, UVVisible Spectroscopy and Conducting Probe Atomic Force Microscopy. Macromolecules 2009, 42, 2981-2987.
Hao, E. H.; Friso, E.; Miotto, G.; Jori, G.; Soncin, M.; Fabris, C.; Sibrian-Vazquez, M.; Vicente, M. G. H. Synthesis and biological investigations of tetrakis(p-carboranylthio–tetra fluorophenyl) chlorine (TPFC). Organic & Biomolecular Chemistry 2008, 6, 3732-3740.
Hao, E. H.; Zhang, M.; Wenbo, E., Kadish, K. M.; Fronczek, F. R.; Courtney, B. H.; Vicente, M. G. H. Synthesis and Spectroelectrochemistry of N-Cobaltacarborane Porphyrin Conjugates. Bioconjugate Chemistry 2008, 19, 2171-2181.
Soncin, M.; Friso, E.; Jori, G.; Hao, E. H.; Vicente, M. G. H.; Miotto, G.; Colautti, P.; Moro, D.; Esposito, J.; Rossi, G.; Fabris, C. Tumor-localizing and radiosensitizing properties of meso-tetra(4-nido-carboranylphenyl)porphyrin (H2TCP). Journal of Porphyrins and Phthalocyanines 2008, 12, 866-875.
Hao, E. H; Fabre, B.; Fronczek, F. R.; Vicente, M. G. H. Syntheses and Electropolymerization of Carboranyl-Functionalized Pyrroles and Thiophenes. Chemistry of Materials. 2007, 19, 6195-6205.
Hao, E. H; Fabre, B.; Fronczek, F. R.; Vicente, M. G. H. Carborane-embedded polythiophenes: New thermally resistant conducting polymers. Chemical Communications. 2007, 4387-4389.
Hao, E. H.; Sibrian-Vazquez, M.; Fronczek, F. R.; Garno, J.; Vicente, M. G. H. Syntheses, Aggregation and Cellular studies of Porphyrin-cobaltacarborane Conjugates. Chemistry, a European Journal, 2007, 32, 9035-9042.
Fabris, C.; Vicente, M. G. H.; Hao, E. H.; Friso, E.; Borsetto, L.; Jori, G.; Miotto, G.; Colautti, P.; Moro, D.; Esposito, J.; Ferretti, A.; Rossi, C. R.; and Soncin, M. Tumour-localizing and -photosensitising Properties of Meso-tetra(4-nido-carboranylphenyl)porphyrin (H2TCP). Journal of Photochemistry & Photobiology, B: Biology. 2007, 89, 131-138.
Jiao, L. J.; Hao, E. H.; Vicente, M. G. H.; Smith, K. M. An Improved Syntheses of 5,5’-Diformyl-2,2’-Bipyrrole. Journal of Organic Chemistry, 2007, 72, 8119-8122.
Jiao, L. J.; Hao, E. H.; Fronczek, F. R.; Vicente, M. G. H.; Smith, K. M. Syntheses of Functionalized Oxacalix[4]arene Porphyrins. Tetrahedron 2007, 63, 4011-4017.
Hao, E. H.; Fronczek, F. R.; Vicente, M. G. H. Carboranylated Pyrroles and Porphyrins via the Suzuki Cross-Coupling Reaction. Chemical Communications 2006, 4900-4902.
Hao, E. H.; Fronczek, F. R.; Vicente, M. G. H. Synthesis of Oxacalixarene-Locked Bisporphyrins and Higher Oligomers. Journal of Organic Chemistry 2006, 71, 1233-1236.
Jiao, L.; Hao, E. H.; Fronczek, F. R.; Vicente, M. G. H.; Smith, K. M. Benzoporphyrins via Olefin Ring-Closure Metathesis Methodology. Chemical Communications 2006, 3900-3902.
Sibrian-Vazquez, M.; Hao, E. H.; Jenson, T.; Vicente, M. G. H. Enhanced Cellular Uptake with a Cobaltacarborane-Porphyrin-HIV-1 Tat 48-60 Conjugate. Bioconjugate Chemistry 2006, 17, 928-934.
Hao, E. H.; Vicente, M. G. H., Expeditious Synthesis of Porphyrin-Cobaltacarborane Conjugates. Chemical Communications 2005, 1306-1308.
Hao, E. H.; Jensen, T. J.; Courtney, B. H.; Vicente, M. G. H., Synthesis and Cellular Studies of Porphyrin-Cobaltacarborane Conjugates. Bioconjugate Chemistry 2005, 16, 1495-1502.
Wang, G. W.; Jiao, L. J.; Hao, E. H.; Lu, Y. M.; Yang, Y. J., Aggregation Properties of an Amphiphilic Methanofullerene Derivative in THF-H2O Solvent Mixtures. Chinese Chemical Letters 2004, 15, (5), 579-582.
Wang, G. W.; Hao, E. H.; Jiao, L. J.; Yan, L. F., Investigation of Solvatochromism and Aggregation Behavior of C60(C4H10N+)I- in Binary Solvent Mixtures. Chinese Science Bulletin 2003, 48, (18), 1938-1942.
Wang, G. W.; Zhang, T. H.; Hao, E. H.; Jiao, L. J.; Murata, Y.; Komatsu, K., Solvent-Free Reactions of Fullerenes and N-alkylglycines with and without Aldehydes under High-Speed Vibration Milling. Tetrahedron 2003, 59, (1), 55-60.

會議報告
Hao, E. H.; Jiao, L. J.; Fronczek, F. R.; Smith, K. M., Vicente, M. G. H. Oxacalixarene-linked porphyrins and their analogs. Org-357, Abstracts of papers, 233rd American Chemical Society, Chicago, IL 2007.
Hao, E. H. and Vicente M. G. H. Syntheses and Characterization of Boronated Porphyrins for Application in BNCT of Cancer. Oral 26, 4th Euroboron, Bremen (Germany), September 2007.
Luguya, R.; Hao, E. H.; Vicente M. G. H.; Smith, K. M. Synthesis of Boronatedhlorins for the Combined PDT and BNCT of Tumors. Oral 48, 4th Euroboron, Bremen (Germany), September 2007.
LeJeune, Z. M.; McKenzie, M.; Daniels, S. L.; Hao, E. H.; Chen, B.; Vicente, J M. G. H.; Garno, C. Controlling the Organization of Porphyrins on Surfaces using Nanolithography. Poster presented at The National FACSS meeting in Memphis, October 2007.
Serem, W. K.; Hao, E. H.; Daniels, S. L.; Fronczek, F. R.; Vicente, M. G. H.; Garno. J. C. Progressive stages of the crystal growth of porphyrin-cobaltcarborane conjugates captured by AFM. Poster presented at The National FACSS meeting in Memphis, October 2007.
Zhang, M.; Wenbo, E., Hao, E. H. Vicente, M. G. H.; Kadish, K. Electrochemistry and Spectroelectrochemistry of free-base Porphyrin-linked Bis(dicarbollyl) cobalt(III) Conjugates. Abstracts of Papers, 62rd American Chemical Society Southwest regional Meeting, Houston, Tx. 2006, INOR-582.
Hao, E. H.; Vicente. M. G. H. Synthesis and Properties of Porphyrin-cobaltacarborane Conjugates. Oral #288, 4rd International Conference on Porphyrins and Phthalocyanines, Rome (Italy), July 2006. Published in Journal of Porphyrins and Phthalocyanines 2006, 10, 288.
Hao, E. H. Fabre, B.; Vicente, M. G. H.; Synthesis and Electrochemistry of Carborane-containing Pyrroles and Thiophenes. Oral INOR-160, 62th Southwest Regional Meeting of the American Chemical Society, Houston (TX), October 2006.
ao, E. H.; Vicente, M. G. H. “Synthesis of Porphyrin-metallacarborane Conjugates.” Poster #682, 3rd International Conference on Porphyrins and Phthalocyanines, New Orleans (LA), July 2004. Published in Journal of Porphyrins and Phthalocyanines 2004, 8, 682.

專 利

Vicente, M. G. H.; Hao, E. H. Boron-Containing Porphyrin Compounds, Their Use in Boron Neutron Capture Therapy, Photodynamic Therapy and Other Uses. PCT. Int. Appl. WO 2006-US41396, 2007.
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