鄭州大學(xué)化學(xué)與分子工程學(xué)院導(dǎo)師：牛云垠 正文

　　
　　姓名：牛云垠　　性別：男　　　出生年月：1960年
　　職稱：教授　　學(xué)院：化學(xué)與分子工程學(xué)院　最后學(xué)歷：博士
　　主要研究方向：超分子，無(wú)機(jī)金屬聚合物，原子簇聚合物結(jié)構(gòu)與性能的關(guān)系
　　
　　牛云垠, 男，42歲，理學(xué)博士，教授，河南省高等學(xué)校骨干教師，鄭州大學(xué)骨干教師，碩士研究生導(dǎo)師，河南省學(xué)術(shù)技術(shù)帶頭人, 鄭州大學(xué)引進(jìn)人才優(yōu)秀個(gè)人。1992-1995年在鄭州大學(xué)化學(xué)系攻讀碩士學(xué)位,從事二茂鐵酰腙類配合物的合成；1999-2002在南京大學(xué)化學(xué)系攻讀博士學(xué)位。主要從事原子簇類化合物的合成與三階非線性光學(xué)性能研究；2002-至今在鄭州大學(xué)化學(xué)系工作，主要研究工作為超分子，無(wú)機(jī)金屬聚合物，原子簇聚合物結(jié)構(gòu)與性能的關(guān)系。

　　九年來(lái)共主持2項(xiàng)國(guó)家自然科學(xué)基金，主持1項(xiàng)河南省杰出青年基金，主持1項(xiàng)中國(guó)博士后科學(xué)基金；并獲1項(xiàng)河南省科技進(jìn)步二等獎(jiǎng)，1項(xiàng)河南省自然科學(xué)優(yōu)秀論文一等獎(jiǎng)，2項(xiàng)二等獎(jiǎng)。 1997年至今，先后在國(guó)內(nèi)外知名刊物發(fā)表學(xué)術(shù)論文58篇，其中SCI論文51篇，核心期刊6篇，截止到2010年底，總的被引用次數(shù)超過(guò)165次。并為國(guó)際期刊Dalton Trans, Cryst. Growth Des., CrystEngComm, New J. Chem., J. Solid State Chem.等的審稿人。Global J. Inorg. Chem.編委，University of Malaya博士論文External Examiner, 申請(qǐng)和參與發(fā)明專利各一項(xiàng)。合作出版專著2部。

　　主持項(xiàng)目：
　　(i) 國(guó)家自然科學(xué)基金，以多氮雜環(huán)陽(yáng)離子為模板的過(guò)渡金屬簇合物互穿體系的定向構(gòu)筑及性能研究（21171148），2012.1.-2015.12。
　　(ii) 國(guó)家自然科學(xué)基金，新型原子簇及其配位聚合物與凝膠玻璃復(fù)合的光學(xué)功能型材料的設(shè)計(jì)、合成（20671083），2007.1.-2009.12。
　　(iii) 河南省杰出青年基金，利用有機(jī)多吡啶配體構(gòu)筑原子簇聚合物的精細(xì)因素研究(0612002800），2006-2008。
　　(iv) 河南省自然科學(xué)基金，有機(jī)不對(duì)稱配體構(gòu)筑的原子簇聚合物及性能研究（511022700），2005.1－2006.12.
　　(v) 河南省骨干教師項(xiàng)目，陽(yáng)離子調(diào)節(jié)型金屬超分子聚合物的合理合成， 2009-2010。
　　(vi) 南京大學(xué)配位化學(xué)重點(diǎn)實(shí)驗(yàn)室開(kāi)放研究基金。2012.1-2013.12

　　省部級(jí)獎(jiǎng)勵(lì)：
　　1．《有機(jī)不對(duì)稱配體構(gòu)筑的原子簇聚合物及性能研究》，獲河南省科學(xué)技術(shù)進(jìn)步二等獎(jiǎng)，牛云垠*，朱路，朱玉，劉修存，王慶麗，郭曉玲，趙付凱. 河南省人民政府，2007.11。
　　2．《含硫雜金屬原子簇聚合物》，獲河南省第九屆自然科學(xué)優(yōu)秀學(xué)術(shù)論文一等獎(jiǎng)，牛云垠*，趙付凱，王慶麗，劉修存，河南省科技廳，河南省科協(xié)，2006.6.

　　編寫專著：
　　(i).《低熱固相化學(xué)反應(yīng)》，普通高等教育“十一五”國(guó)家級(jí)規(guī)劃教材，忻新泉，周益明，牛云垠編著，高等教育出版社。2010.7. ISBN 978-7-04-028695-3.
　　(ii). A Systematic Design and Facile Construct of Tetraphenylborate Salt Supramoleculer Polymers with 1, ω-bis(pyridinium)Alkanes Dications. Advances in Materials Science Research. Volume 6, Fu-Kai Zhao, Xiu-Cun Liu, Yun-Yin Niu,* Dong-Hui Wei, Hong-Wei Hou, Ming-Sheng Tang, Yao-Ting Fan, Yu Zhu. Nova Science Publishers, 2011. Volume 6, v.6. 213, 30

　　申請(qǐng)專利：
　　(i)．一種多鉬酸化合物及其制備方法， 牛云垠,* 呂效銳，侯紅衛(wèi)，國(guó)家發(fā)明專利，專利號(hào)ZL 200810140503.3.已授權(quán)。
　　(ii)．氟康唑配位聚合物、制備方法及用途。侯紅衛(wèi),* 韓華云，樊耀亭，孟祥茹，牛云銀， 200410010159.8, 國(guó)家發(fā)明專利，0150703064。已授權(quán)

　　發(fā)表主要論文
　　1. Yong-Zhen Qiao, Jun-Ming Yue, Xiu-Cun Liu and Yun-Yin Niu.* Three novel cation-templated metal thiocyanates with 1-2D polypseudorotaxane frameworks. CrystEngComm, 2011, 13, 6885-6892.
　　2. Jun-Ming Yue, Yun-Yin Niu,* Bing Zhang, Seik-Weng Ng and Hong-Wei Hou. “Four novel metal coordination polymers directed by 1,1′-dibutyl-4,4′-bipyridinium dibromide (BBP) and their framework dependent luminescent properties.” CrystEngComm. 2011, 13(7), 2571-2577.
　　3. Niu, Yun-Yin;* Wang, Ling-Fang; Lv, Xiao-Rui; Du, Hai-Juan; Qiao, Yong-Zhen; Wang, Hong-Mei; Song, Li-Sha; Wu, Ben-Lai; Hou, Hong-Wei; Ng, Seik Weng. Construction and isomeric transformation of polyoxometalates directed by 1, w?-bis(pyridinium)alkane templates. CrystEngComm. 2011, 13(16), 5071-5081.
　　4. Han, Yi; Zhang, Zhenhua; Liu, Yanyan; Niu, Yunyin;* Ding, Degang; Wu, Benlai; Hou, Hongwei;* Fan, Yaoting. External Template-Assisted Self-Assembly:Design and Synthesis of 4,4'-bipy-Based Mo(W)/Cu/S Heterothiometallic Polymeric Clusters Directed by 1,1'-Bis(pyridinium)methylene Cation. Cryst. Growth Des. 2011, 11(8), 3448-3455.
　　5. Zhen-Hua Zhang, Hong-Mei Wang, Yun-Yin Niu,* Ben-Lai Wu, Seik-Weng Ng, Hong-Wei Hou. Design and the cation-templated self-assembly on the [MoOS3Cu3]+ based supramolecular polymeric clusters. Inorg. Chem. Commun. 2011, 14, 1783–1787.
　　6. Zhenhua Zhang; Yunyin Niu;* Seikweng Ng; Benlai Wu; HongWei Hou. Template construction of a series of supramolecular coordination polymers via 6,7-dihydro-5H-[1,4]diazepino[1,2,3,4-lmn][1,10]phenanthroline-4,8-diium cation. J. Coord. Chem. 2011, 64(10), 1683–1694.
　　7. Jun-Ming Yue, Na Xu, Zhen-Hua Zhang, Wen-Long Dong, Yun-Yin Niu,* Hong-Wei Hou. Role of spacers and substituents in the self-assembly process: Syntheses and characterization of two novel thiocyanatocuprates polymers. Inorg. Chem. Commun. 2010, 13, 1534–1537.
　　8. Yun-Yin Niu,* Ben-Lai Wu, Qing-Li Wang, Xiao-Ling Guo, Hong-Yun Zhang, Hong-Wei Hou, Yi Han, Ling-Fang Wang. “Construction of 1–2D CuI(or CuII) metal–organic architectures with metal thiocyanates and bipyridyl spacers: Syntheses, structures, and thermal properties.” Inorg. Chim. Acta. 2009, 362, 556–562.
　　9. Xiao-Rui Lv, Fu-Kai Zhao, Xiao-Ling Guo, Yun-Yin Niu*, Na Xu, Hong-Wei Hou,Yao-Ting Fan, Dong Sun, Yu Zhu. Hydrothermal synthesis, structure and fluorescent property of a novel cuprous thiocyanate inorganic polymer directed by 1,5-bis(pyridinium) pentane cation. Inorg. Chem. Commun. 2009，12，653–656.
　　10. Yun-Yin Niu,* Ben-Lai Wu, Xiao-Ling Guo, Ying-Lin Song, Xiu-Cun Liu,Hong-Yun Zhang, Hong-Wei Hou, Cao-Yuan Niu, And Seik-Weng Ng. “A Systematic Design And Facile Construct Of Metal Pseudohalide Frameworks Directed By 1,Ω-Bis(Pyridinium)Alkane Cations.” Cryst. Growth Des. 2008, 8, 2393–2401.
　　11. Ping Zhang, Yun-Yin Niu*, Ben-Lai Wu, Hong-Yun Zhang*, Cao-Yuan Niu, Hong-Wei Hou. 2D frameworks of Cu(II) and Zn(II) organo-metallic polymers self-assembled with N,N'-(1,2-phenylene)diisonicotinamide: Syntheses, structures, photoluminescence, and thermal properties. Inorg. Chim. Acta. 2008, 361, 2609–2615.
　　12. Yunyin Niu, Ning Zhang, Hongwei Hou,* Yu Zhu, Mingsheng Tang and Seik Weng Ng Adaptable metal cluster block: Facile construction of photoluminescent CuI coordination polymeric clusters with metal (I) iodides. J. Mol. Struct. 2007，827，195-200.
　　13. Yunyin Niu, Yinglin Song, Ning Zhang, Hongwei Hou,* Deji Che, Yaoting Fan, Yu Zhu, Chunying Duan, “Reactivity of Polyiodides toward 1, 3-Bis(4-Pyridyl)Propane (bpp): a New CuI Cluster Polycatenane Framework and a Novel 2D AgI Cluster Motif.”Eur. J. Inorg. Chem, 2006, 11，2259-2267.
　　14. Yunyin Niu*, Zhongjun Li, Yinglin Song, Mingsheng Tanga, Benlai Wu, Xinquan Xin. “Three-dimensional molecular network, [{Cu(dps)2(SO4)} × 3H2O×DMF]n, and its different third-order NLO performance (dps = 4,4’-dipyridyl sulfide).” J. Solid State Chem.，2006，179，4003-4010.
　　15. Yunyin Niu*, Yinglin Song, Qingli Wang, Xiaoling Guo, Yu Zhu and Hongwei Hou. “Synthesis, Crystal Structure, and Optical Limiting Effect of a Cu(I) Coordination Polymeric Cluster Bridged by Chiral-carbon Skeleton Bipyridyl Ligand”. Chem. Lett. 2006, 35 (6), 650-651.
　　16. Yunyin Niu, Yinglin Song, Hongwei Hou,* Yu Zhu. “Synthesis, Structure and Large Optical Limiting Effect of the First Coordination Polymeric Cluster Based on {I@[AgI(inh)]6} Hexagram Block.” Inorg. Chem. 2005, 44(7), 2553-2556.
　　17. Yunyin Niu, Ning Zhang , Yinglin Song , Hongwei Hou,* Yaoting Fan , Yu Zhu. “The syntheses, crystal structures and optical limiting effects of transition metal complexes bridged by bipyridyl-based ligands.” Inorg. Chem. Commun. 2005, 8，495-457.
　　18. Yunyin Niu, Hegen Zheng, Hongwei Hou, Xinquan Xin.* “Heterothiometallic polymeric clusters”. Coord. Chem. Rev. 2004, 248, 169-192.
　　19. Yun-Yin Niu, Ying-Lin Song, Jie Wu,Hongwei Hou,* and Yu Zhu. “Nonlinear polymeric effect: synthesis, crystal structure and nonlinear optical properties of a new mercury iodide adduct polymer [Hg(bpfb)I2]n×2DMF (bpfb = N,N’-bis(4-pyridyl formamide)-1,4-benzene)” Inorg. Chem. Commun. 2004, 7, 471-474.
　　20. Ying-Lin Song, Yun-Yin Niu, Hong-Wei Hou,* Yu Zhu.“The synthesis, crystal structure and optical limiting properties of ZnI2-pyrazine adduct polymer linked by iodine···iodine supramolecular soft-soft interaction.” J. Mol. Struct. 2004, 689/1-2, 69-74.
　　21. Yunyin Niu, Yinglin Song, Hegen Zheng, Feng Li, Hoongkun Fun and Xinquan Xin,* “The first heterothiometallic complex of [N(SPPh2)2]-: Synthesis, structure and nonlinear optical effect of dodecanuclear cluster {[Et4N]4 Mo4Cu­4S12O4[Cu(NSPPh2)2]4}”, New J. Chem. 2001, 257, 945-948.
　　22. Qianfeng Zhang, Yunyin Niu, W. H. Leung, Yinglin Song, Ian D. Williams Xinquan Xin.* “Synthesis of a 2D polymeric cluster {[NEt4][Mo2O2S6Cu6 I3 (4,4-bipy)5]·MeOH·H2O}n with a significant improvement of optical limiting effect.” Chem. Commun., 2001, 1126-1127.
　　23. Yunyin Niu, Tian Niu Chen, Shixiong Liu, Yinglin Song, Yu Xiao Wang, Ziling Xue, Xinquan Xin.* “Reactivity of the [MoS4Cu6Br8]4- anion toward polyarylphosphorus ligands: synthesis, characterization and nonlinear optical properties of [MoS4(Cudppf)2]·2DMF·CH3CN and [MoS4Cu2(Ph2PPy)4] [dppf = 1, 1-bis (diphenylphosphino)ferrocene; Ph2PPy = 2-(diphenylphosphino) pyridine]” ，J. Chem. Soc., Dalton Trans., 2002, 1980–1984.
　　24. Yunyin Niu, Hongwei Hou, * Yongli Wei, Yaoting Fan, Yu Zhu, Chenxia Du & Xinquan. Xin. “A Linear Piperazine-Pyridine Ligand and Its Hg Coordination Polymer”, Inorg. Chem. Commun. 2001, 4(7), 358-361.
　　25. Yunyin Niu, Yuxiao Wang, Yinglin Song, Shixiong Liu, Hegen Zheng, Xinquan Xin.* ”synthesis, structure and optical refractive effect of dibutyltin(IV) complex of [Ph2P(S)NP(S)Ph2]- .” Chem. Lett., 2001, 1004-1005.
　　26. Yunyin Niu, Yinglin Song , Shixiong Liu, and Xinquan Xin. “ Synthesis, crystal structure and large nonlinear refractive properties of mercury iodide adduct with 1,1-bis(diphenylphosphino) ferrocene.” Z. Anorg. Allg. Chem. 2002, 628, 179-182.
　　27. Yunyin Niu, Yinglin Song, Tianniu Chen, Ziling Xue, Xinquan Xin.* “A novel HgI2 adduct with bipyridyl ligand: synthesis, structure and optical refractive effect of [HgI2(4,4-azobipyridine)]n”, CrystEngComm, 2001, 36, 1-3.

　　聯(lián)系方式:Email: niuyy@zzu.edu.cn QQ: 642988550
　　通訊地址: College of Chemistry and Molecular Engineering, Zhengzhou University, 75 Daxue Road, Zhengzhou 450052, China

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